PH Control Principles in Different Stages of Reverse Osmosis Operation
Reverse Osmosis (RO) technology has become a cornerstone in modern water treatment systems, widely applied in industrial, municipal, and commercial projects. One of the key operational parameters in maintaining stable performance and protecting the RO membranes is pH control. Proper pH regulation during the different stages of RO operation—pretreatment, system operation, and cleaning—directly impacts system efficiency, water quality, and membrane lifespan.

Importance of pH in RO Systems
RO membranes are sensitive to extreme pH levels. While most polyamide thin-film composite (TFC) membranes can generally operate within a pH range of 4–11, short-term cleaning procedures allow exposure to a wider range (typically pH 2–12). If pH is not properly managed, scaling, fouling, or hydrolysis of the membrane material may occur, reducing salt rejection and shortening service life.
pH Control in Different Stages
- Pretreatment Stage
- Objective: Prevent scaling and fouling inside the RO system.
- Method: Adjust feedwater pH to reduce precipitation risks from hardness ions such as calcium carbonate, calcium sulfate, or silica. For example, acid dosing (sulfuric or hydrochloric acid) is commonly used to lower pH, thereby keeping salts soluble and minimizing scaling.
- Operation Stage
- Objective: Maintain optimal desalination performance while protecting the membrane.
- Method: During operation, feedwater pH is kept stable within the recommended range of the membrane manufacturer. Stability ensures that the polyamide active layer maintains its integrity, achieving high salt rejection and consistent permeate water quality.
- Cleaning Stage (CIP – Clean-In-Place)
- Objective: Remove accumulated scale, organic fouling, or biological growth.
- Method:
- Acid cleaning solutions (low pH, around 2–4) dissolve inorganic scaling such as calcium carbonate or iron deposits.
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Alkaline cleaning solutions (high pH, around 10–12) remove organic fouling, oils, and biological matter.
Alternating between acidic and alkaline cleaning ensures full system recovery without damaging the membrane.
HID MEMBRANE CO., LTD.: Innovating RO Membrane Solutions
HID MEMBRANE CO., LTD. is a professional manufacturer of high-performance RO membranes, dedicated to delivering reliable solutions for desalination, industrial water treatment, and commercial purification. The company’s membranes are engineered with robust polyamide thin-film technology, offering:
- Wide pH Tolerance for safe cleaning and maintenance.
- High Salt Rejection to ensure superior water quality.
- Durable Performance even under challenging water chemistry conditions.
With a strong focus on innovation and quality, HID MEMBRANE provides tailored technical support, including guidance on optimal pH control strategies to maximize system efficiency and extend membrane service life.
Conclusion
pH control is fundamental in every stage of reverse osmosis operation. From preventing scaling in pretreatment, ensuring stable performance during operation, to effective chemical cleaning, maintaining the correct pH range safeguards both the water quality and the longevity of the RO membranes. HID MEMBRANE CO., LTD. continues to support industries worldwide with advanced membrane technology and expert knowledge, helping clients achieve sustainable and cost-effective water treatment solutions.
